Padmé first met Obi-Wan, shortly after the Invasion of Naboo started, when he and his mentor, Qui-Gon Jinn rescued her from the Trade Federation's battle droids, they do not have much interaction with each other. However, throughout the Clone Wars the two become close friends.
In Star Wars: Revenge of the Sith, Padmé's friendship with Obi-Wan became strained, after Anakin told her of Obi-Wan's manipulations to use him as a spy for his own purposes, she did not believe him when he told her of husband's dark deeds, mainly because she was in denial and partly because of what Anakin told her, to reassure herself that what he had said was not true, she traveled to Mustafar to ask Anakin herself; unknown to Padmé, Obi-Wan had stowed away on her Naboo star skiff, so he could find Vader and kill him.
Before Padmé's death, she told Obi-Wan that there was still good left in Anakin and one day he can be redeemed, but Obi-Wan didn't believe her. Padme's belief in her husband proved right when he sacrificed himself to save their son, Luke.
Thank you Curtis (Obi Wan Kenobi) for collaborating with me on this special project.
Growing up in Los Angeles in the 70s/80s we visited Disneyland on a regular basis and often after school, before "Annual Passes".